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Beilstein J. Org. Chem. 2013, 9, 866–876, doi:10.3762/bjoc.9.100
Graphical Abstract
Scheme 1: Synthesis of 4'-ethynyl-2,2':6',2''-terpyridine (5).
Scheme 2: Synthesis of tpy-functionalized dendritic oligothiophenes 8 and 9.
Scheme 3: Synthesis of homoleptic Ru(II) complexes 1 and 2.
Figure 1: (a) Absorption spectra of ligands and their corresponding Ru(II)-dendrimers in acetonitrile solutio...
Figure 2: Electronic distribution of the frontier orbitals (HOMO, HOMO-1 and LUMO) for complexes 1 (a) and 2 ...
Figure 3: CV of 1.0 mM solutions of ligands (a) and complexes (b) in anhydrous dichloromethane (oxidation) an...
Beilstein J. Org. Chem. 2012, 8, 683–692, doi:10.3762/bjoc.8.76
Scheme 1: Synthesis of 3-azidothiophene 2.
Scheme 2: One-pot, two-step procedure to give a dithienyl-1,2,3-triazole co-oligomer 5. See Table 1 for detailed con...
Scheme 3: Synthesis of 1,4-bis[4-(thiophen-2-yl)-1H-1,2,3-triazol-1-yl]-benzene 21.
Figure 1: UV–vis spectra of 5, 10 and 11 (a) and 12–14 (b) in dichloromethane ([c] = 5 × 10−5 M) at room temp...
Figure 2: HOMO–LUMO energy level diagram for thiophene–triazole co-oligomers 5, 6, 10–14.
Figure 3: Cyclic voltammogram of bithienyl-triazole 14 in dichloromethane/TBAPF6 (0.1 M) versus Fc/Fc+ at 100...